NMR spectroscopic investigation of agarose oligomers produced by an alpha-agarase.
Rochas C, Potin P, Kloareg B.
Centre de Recherches sur le Macromolecules Végétales, CNRS-UPR 5301, Grenoble, France.
The 13C NMR signals of various even and odd agarose oligosaccharides with either D-galactose or 3,6-anhydro-alpha-L-galactose at the reducing end have been assigned. The chemical shifts in water of the agaro- and the neoagaro-oligosaccharides are compared and the influence of dimethyl sulfoxide on the chemical structure of the agaro-oligosaccharides is reported. The 3,6-anhydro-L-galactose residue at the reducing end of agaro-oligosaccharides is in the hydrated form.
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PMID: 8156559 [PubMed - indexed for MEDLINE]